全文获取类型
收费全文 | 6547篇 |
免费 | 218篇 |
国内免费 | 55篇 |
专业分类
化学 | 4005篇 |
晶体学 | 49篇 |
力学 | 107篇 |
数学 | 1295篇 |
物理学 | 1364篇 |
出版年
2023年 | 25篇 |
2022年 | 51篇 |
2021年 | 154篇 |
2020年 | 129篇 |
2019年 | 191篇 |
2018年 | 205篇 |
2017年 | 173篇 |
2016年 | 253篇 |
2015年 | 216篇 |
2014年 | 216篇 |
2013年 | 481篇 |
2012年 | 430篇 |
2011年 | 534篇 |
2010年 | 373篇 |
2009年 | 308篇 |
2008年 | 439篇 |
2007年 | 407篇 |
2006年 | 367篇 |
2005年 | 354篇 |
2004年 | 304篇 |
2003年 | 228篇 |
2002年 | 166篇 |
2001年 | 67篇 |
2000年 | 73篇 |
1999年 | 72篇 |
1998年 | 61篇 |
1997年 | 50篇 |
1996年 | 76篇 |
1995年 | 47篇 |
1994年 | 41篇 |
1993年 | 47篇 |
1992年 | 39篇 |
1991年 | 26篇 |
1990年 | 13篇 |
1989年 | 13篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 11篇 |
1985年 | 13篇 |
1984年 | 11篇 |
1983年 | 17篇 |
1982年 | 14篇 |
1981年 | 13篇 |
1980年 | 5篇 |
1979年 | 8篇 |
1978年 | 11篇 |
1977年 | 12篇 |
1976年 | 6篇 |
1975年 | 11篇 |
1973年 | 5篇 |
排序方式: 共有6820条查询结果,搜索用时 62 毫秒
21.
22.
Anastasia O. Kolesnikova Dmitry A. Kornilov Aidar T. Gubaidullin Vladimir D. Kiselev 《国际化学动力学杂志》2020,52(5):301-309
The kinetic parameters and enthalpies of the Diels–Alder reactions between cyclopentadiene and 2,3-dicyano-1,4-benzoquinone leading to the formation of two different monoadducts and bisadduct were determined. The stability of adducts is compared. Monoadduct appears to be thermodynamically more stable than the bisadduct. Comparison with the other Diels–Alder reactions studied previously allows us to conclude that the heat effects upon formation of the considered Diels–Alder adducts are the lowest in comparison with all the studied dienophiles. 相似文献
23.
Dr. Shuangyan Wu Dr. Mingchang Zhu Dr. Ying Zhang Prof. Marina Kosinova Prof. Vladimir P. Fedin Prof. Enjun Gao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(14):3137-3144
As a hot topic of global concern, the distinguishing and detecting of antibiotic pollution is crucial owing to its adverse effect on ecosystems and human health stemming from excessive use and poor management. Herein, a water-stable lanthanide coordination polymer sensor (Dy-TCPB) with multiple emitting centers is prepared. The versatile Dy-TCPB can conveniently differentiate various antibiotics, and displays a self-calibration luminescent response to nitrofurazone (NFZ) and furazolidone (FZD). Each antibiotic exhibits notable correlation to a unique combination of the two ligand-to-Dy ion emission intensity ratios, enabling two-dimensional fingerprint recognition. Furthermore, the novel self-calibration sensor demonstrates effective recognition of NFZ and FZD with excellent sensitivity and selectivity, and detection limits as low as 0.0476 and 0.0482 μm for NFZ and FZD, respectively. The synthetic approach for the fabrication of a singular coordination polymer exhibiting multiple emissions provides a promising strategy for the development of facile and effective ratiometric sensors. 相似文献
24.
Prof. Vladimir I. Bregadze Prof. Igor B. Sivaev Ravindra Dhar Dubey Prof. Andrey Semioshkin Dr. Akim V. Shmal'ko Dr. Irina D. Kosenko Kseniya V. Lebedeva Prof. Swadhin Mandal Prasannakumar Sreejyothi Arindam Sarkar Prof. Zheyu Shen Prof. Aiguo Wu Prof. Narayan S. Hosmane 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(61):13832-13841
A series of boron-containing lipids were prepared by reactions of cyclic oxonium derivatives of polyhedron boranes and metallacarboranes (closo-dodecaborate anion, cobalt and iron bis(dicarbollides)) with amine and carboxylic acids which are derived from cholesterol. Stable liposomal formulations, on the basis of synthesized boron-containing lipids, hydrogenated soybean l -α-phosphatidylcholine and (HSPC) 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000] (DSPE-PEG) as excipients, were prepared and then characterized by dynamic light scattering (DLS) that revealed the formation of particles to be smaller than 200 nm in diameter. The resulting liposomal formulations showed moderate to excellent loading and entrapment efficiency, thus justifying the design of the compounds to fit in the lipid bilayer and ensuring ease of in vivo use for future application. The liposomal formulations based on cobalt and iron bis(dicarbollide)-based lipids were found to be nontoxic against both human breast normal epithelial cells MCF-10A and human breast cancer cells MCF-7. 相似文献
25.
Dr. Vladimir V. Shilovskikh Alexandra A. Timralieva Pavel V. Nesterov Dr. Alexander S. Novikov Dr. Petr A. Sitnikov Prof. Elizaveta A. Konstantinova Prof. Alexander I. Kokorin Prof. Ekaterina V. Skorb 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(70):16603-16610
In the last two decades, a large number of self-assembled materials were synthesized and they have already found their way into large-scale industry and science. Hydrogen-bond-based supramolecular adducts are found to have unique properties and to be perfect host structures for trapping target molecules or ions. Such chemical systems are believed to resemble living matter and can substitute a living cell in a number of cases. Herein, a report on an organic material based on supramolecular assembly of barbituric acid and melamine is presented. Surprisingly, the structure is found to host and stabilize radicals under mild conditions allowing its use for biological applications. The number of free radicals is found to be easily tuned by changing the pH of the environment and it increases when exposed to light up to a saturation level. We describe a preparation method as well as stability properties of melamine–barbiturate self-assembly, potentiometric titration, and hydrogen ions adsorption data and EPR spectra concerning the composite. 相似文献
26.
Voronina Anna V. Bajtimirova Marina O. Semenishchev Vladimir S. 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):913-920
Journal of Radioanalytical and Nuclear Chemistry - The effect of humic acids (HA) on 137Cs and 90Sr uptake by natural and modified aluminosilicates was studied under the conditions of radioactively... 相似文献
27.
28.
29.
30.
The electrophoretic mobility change of desferrioxamine B (DFO) was monitored by UV absorption spectrophotometry upon increasing the thorium(IV) concentration in the background electrolyte at two acidities ([HClO4]Tot = 0.0316 and 0.0100 M). These data enabled to assess the speciation model and to determine the equilibrium constant of [Th(DFO)H2]3+ at fixed ionic strength (I = 0.1 M (H,Na)ClO4). Affinity capillary electrophoresis (ACE) turned out to be most helpful in identifying the complexed species by ascertaining its charge and protonation state. The assignment of the correct stoichiometry relied on the reliable estimation of the electrophoretic mobility by assuming similar hydrodynamic radii for (DFO)H4+ and the chelate. The value of the apparent equilibrium constant (log β112 = 38.7 ± 0.4) obtained by ACE compares favorably well with those reported in the literature for thorium and a range of other metal ions, according to a linear free-energy relationship. This method is useful for studying metal-ligand binding equilibria and provides valuable information for further modelling the behavior of tetravalent actinides under environmental conditions. Structural information about the prevalent solution species in acidic conditions was gained by DFT calculations, confirming the bishydroxamato coordination mode of Th4+ by the diprotonated ligand. 相似文献